Wooden Houses In the title compound, C14H12ClN3S, the dihedral angle between the terminal benzene rings is 56.6 (2)°; the benzene rings lie to the same side of the molecule.The major twist in the molecule occurs around the Car—N bond (ar is aromatic) [C—N—C—C = 49.9 (5)°].
The configuration about the N=C bond [1.271 (4) Å] is E.The amine H atoms lie on opposite Antenna Mounting Bracket sides of the molecule with one forming an intramolecular N—H.N(imine) hydrogen bond and an S(5) ring.
In the crystal, centrosymmetric dimers are formed via {.HNC=S}2 synthons.